CA2146063A1 - Use of alkaline proteases in industrial textile washing processes - Google Patents
Use of alkaline proteases in industrial textile washing processesInfo
- Publication number
- CA2146063A1 CA2146063A1 CA002146063A CA2146063A CA2146063A1 CA 2146063 A1 CA2146063 A1 CA 2146063A1 CA 002146063 A CA002146063 A CA 002146063A CA 2146063 A CA2146063 A CA 2146063A CA 2146063 A1 CA2146063 A1 CA 2146063A1
- Authority
- CA
- Canada
- Prior art keywords
- washing processes
- alkaline proteases
- textile washing
- industrial textile
- proteases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 108091005658 Basic proteases Proteins 0.000 title 1
- 239000004753 textile Substances 0.000 title 1
- 238000005406 washing Methods 0.000 title 1
- 102000035195 Peptidases Human genes 0.000 abstract 3
- 108091005804 Peptidases Proteins 0.000 abstract 3
- 239000004365 Protease Substances 0.000 abstract 3
- 241000193830 Bacillus <bacterium> Species 0.000 abstract 2
- 125000003275 alpha amino acid group Chemical group 0.000 abstract 2
- 241000193375 Bacillus alcalophilus Species 0.000 abstract 1
- 150000001413 amino acids Chemical class 0.000 abstract 1
- 238000004900 laundering Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 102220007992 rs147391618 Human genes 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/14—Hydrolases (3)
- C12N9/48—Hydrolases (3) acting on peptide bonds (3.4)
- C12N9/50—Proteinases, e.g. Endopeptidases (3.4.21-3.4.25)
- C12N9/52—Proteinases, e.g. Endopeptidases (3.4.21-3.4.25) derived from bacteria or Archaea
- C12N9/54—Proteinases, e.g. Endopeptidases (3.4.21-3.4.25) derived from bacteria or Archaea bacteria being Bacillus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Zoology (AREA)
- Genetics & Genomics (AREA)
- Biotechnology (AREA)
- Biochemistry (AREA)
- Biomedical Technology (AREA)
- Medicinal Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Molecular Biology (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Detergent Compositions (AREA)
- Enzymes And Modification Thereof (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
Abstract
The use of alkaline bacillus proteases in commercial laundry methods and compositions containing these proteases for commercial laundering are described. The alkaline bacillus proteases are obtained from Bacillus alcalophilus HA1(DSM 5466) and have an amino-acid sequence which differs from the amino-acid sequence of SEQ ID No:1 (Figure 1) by at least one amino-acid replacement selected from the group consisting of Q12R, N74R, M216Q; N237P and T249R.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4411223.8 | 1994-03-31 | ||
DE4411223A DE4411223A1 (en) | 1994-03-31 | 1994-03-31 | Use of alkaline proteases in commercial textile washing processes |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2146063A1 true CA2146063A1 (en) | 1995-10-01 |
CA2146063C CA2146063C (en) | 2006-03-21 |
Family
ID=6514333
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002186764A Expired - Lifetime CA2186764C (en) | 1994-03-31 | 1995-03-27 | High-alkaline protease and its use |
CA002146063A Expired - Lifetime CA2146063C (en) | 1994-03-31 | 1995-03-31 | Use of alkaline proteases in industrial textile washing processes |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002186764A Expired - Lifetime CA2186764C (en) | 1994-03-31 | 1995-03-27 | High-alkaline protease and its use |
Country Status (13)
Country | Link |
---|---|
US (3) | US6190904B1 (en) |
EP (2) | EP0753058B1 (en) |
JP (2) | JPH10505741A (en) |
CN (1) | CN1148406A (en) |
AT (2) | ATE269404T1 (en) |
AU (2) | AU710223B2 (en) |
BR (2) | BR9507237A (en) |
CA (2) | CA2186764C (en) |
DE (3) | DE4411223A1 (en) |
DK (2) | DK0753058T3 (en) |
FI (2) | FI116681B (en) |
NZ (1) | NZ282821A (en) |
WO (1) | WO1995027049A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6187739B1 (en) | 1995-09-21 | 2001-02-13 | Henkel Kommanditgesellschaft Auf Aktien | Paste-form washing and cleaning agents |
US6248708B1 (en) | 1996-09-05 | 2001-06-19 | Henkel-Ecolab Gmbh & Co. Ohg | Paste-form detergent containing a mixture of ethoxylated alcohols |
US6380140B1 (en) | 1996-04-20 | 2002-04-30 | Henkel Komm.Nditgesellschaft Auf Aktien | Enzyme granules containing phosphated starch |
Families Citing this family (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4411223A1 (en) * | 1994-03-31 | 1995-10-05 | Solvay Enzymes Gmbh & Co Kg | Use of alkaline proteases in commercial textile washing processes |
JP4030603B2 (en) * | 1995-11-02 | 2008-01-09 | ノボザイムス アクティーゼルスカブ | Alkaline protease, method for producing the same, use and microorganism producing the protease |
CN1136311C (en) | 1996-11-04 | 2004-01-28 | 诺沃奇梅兹有限公司 | Subtilase variants and compositions |
CN1165615C (en) | 1996-11-04 | 2004-09-08 | 诺维信公司 | Subtilase variants and compositions |
BR9712489A (en) * | 1996-12-04 | 1999-10-19 | Novo Nodisk Biochem North Amer | Process for wet cleaning of cellulosic material and cellulosic material |
DE19703364A1 (en) | 1997-01-30 | 1998-08-06 | Henkel Ecolab Gmbh & Co Ohg | Paste-like detergent and cleaning agent |
KR20010023468A (en) | 1997-08-29 | 2001-03-26 | 한센 핀 베네드, 안네 제헤르, 웨이콥 마리안느 | Protease variants and compositions |
CA2301851C (en) | 1997-08-29 | 2012-08-07 | Novo Nordisk A/S | Protease variants and compositions |
ES2367505T3 (en) * | 1997-10-23 | 2011-11-04 | Danisco Us Inc. | PROTEASE VARIANTS WITH MULTIPLE SUBSTITUTIONS WITH ALTERED NET LOAD FOR USE IN DETERGENTS. |
EP1032655B1 (en) | 1997-11-21 | 2005-06-29 | Novozymes A/S | Protease variants and compositions |
US6773907B2 (en) | 1997-11-21 | 2004-08-10 | Peter Kamp Hansen | Subtilase enzymes |
US6780629B2 (en) | 1997-11-21 | 2004-08-24 | Novozymes A/S | Subtilase enzymes |
DE19857687A1 (en) | 1998-12-15 | 2000-06-21 | Henkel Ecolab Gmbh & Co Ohg | Pasty detergent |
EP1803817B1 (en) | 1998-12-18 | 2011-04-06 | Novozymes A/S | Subtilase enzymes of the I-S1 and I-S2 sub-groups having an additional amino acid residue in an active site loop region |
DE19904512A1 (en) * | 1999-02-04 | 2000-08-17 | Henkel Ecolab Gmbh & Co Ohg | Method for cleaning refillable bottles |
WO2000071690A1 (en) | 1999-05-20 | 2000-11-30 | Novozymes A/S | Subtilase enzymes of the i-s1 and i-s2 sub-groups having at least one additional amino acid residue between positions 128 and 129 |
AU4392500A (en) | 1999-05-20 | 2000-12-12 | Novozymes A/S | Subtilase enzymes of the i-s1 and i-s2 sub-groups having at least one additionalamino acid residue between positions 132 and 133 |
EP1183339B2 (en) | 1999-05-20 | 2013-03-13 | Novozymes A/S | Subtilase enzymes of the i-s1 and i-s2 sub-groups having at least one additional amino acid residue between positions 129 and 130 |
EP1183341B2 (en) | 1999-05-20 | 2012-05-02 | Novozymes A/S | Subtilase enzymes of the i-s1 and i-s2 sub-groups having at least one additional amino acid residue between positions 127 and 128 |
ATE402996T1 (en) | 1999-05-20 | 2008-08-15 | Novozymes As | SUBTILASE ENZYMES OF THE I-S1 AND I-S2 SUBGROUPS WITH AT LEAST ONE ADDITIONAL AMINO ACID RESIDUE BETWEEN POSITIONS 125 AND 126 |
AU4392800A (en) | 1999-05-20 | 2000-12-12 | Novozymes A/S | Subtilase enzymes of the i-s1 and i-s2 sub-groups having at least one additionalamino acid residue between positions 126 and 127 |
US6727085B2 (en) | 1999-12-15 | 2004-04-27 | Fanoe Tina Sejersgaard | Subtilase variants having an improved wash performance on egg stains |
US6777218B1 (en) | 2000-03-14 | 2004-08-17 | Novozymes A/S | Subtilase enzymes having an improved wash performance on egg stains |
MXPA02010643A (en) * | 2000-04-26 | 2004-05-17 | Land O Lakes Inc | A method of treating soy proteins and a soy protein product produced by this method. |
CN1303210C (en) * | 2000-12-29 | 2007-03-07 | 四川大学 | Detersile proteinase and its production process and usage and microbe producing the said proteinase |
US7183248B2 (en) * | 2001-08-23 | 2007-02-27 | Treyco Supply Co. | Enzymatic cleaner having high pH stability |
WO2003040459A1 (en) * | 2001-11-02 | 2003-05-15 | Novozymes North America, Inc. | Modification of printed and dyed materials |
DE10162727A1 (en) * | 2001-12-20 | 2003-07-10 | Henkel Kgaa | New alkaline protease from Bacillus gibsonii (DSM 14391) and washing and cleaning agents containing this new alkaline protease |
DE10162728A1 (en) | 2001-12-20 | 2003-07-10 | Henkel Kgaa | New alkaline protease from Bacillus gibsonii (DSM 14393) and washing and cleaning agents containing this new alkaline protease |
DE10163883A1 (en) * | 2001-12-22 | 2003-07-10 | Henkel Kgaa | New alkaline protease from Bacillus sp. (DSM 14390) and detergents and cleaning agents containing this new alkaline protease |
DE10163884A1 (en) * | 2001-12-22 | 2003-07-10 | Henkel Kgaa | New alkaline protease from Bacillus sp. (DSM 14392) and detergents and cleaning agents containing this new alkaline protease |
EP2339017A3 (en) | 2002-03-29 | 2011-10-12 | Genencor International, Inc. | Enhanced protein expression in bacillus |
JP4694966B2 (en) * | 2002-07-30 | 2011-06-08 | ジェネンコー・インターナショナル・インク | Formulations that reduce aerosol production |
DE10262050A1 (en) * | 2002-09-05 | 2004-09-23 | Technische Universität Dresden | Genetic variants in the MMP-2 gene as etiological factors of various diseases |
WO2004099401A1 (en) | 2003-05-07 | 2004-11-18 | Novozymes A/S | Variant subtilisin enzymes (subtilases) |
EP1678296B1 (en) | 2003-10-23 | 2011-07-13 | Novozymes A/S | Protease with improved stability in detergents |
WO2006033668A2 (en) * | 2004-04-09 | 2006-03-30 | Genencor International, Inc. | Pcka modifications and enhanced protein expression in bacillus |
US20070010416A1 (en) * | 2004-10-22 | 2007-01-11 | Novozymes A/S | Protease with improved stability in detergents |
DE602005009031D1 (en) * | 2005-03-22 | 2008-09-25 | Gumlink As | METHOD FOR CLEANING A SURFACE ATTACHED TO AT LEAST ONE RUBBER LUMP |
CN101460618A (en) | 2006-04-20 | 2009-06-17 | 诺维信公司 | Savinase variants having an improved wash performance on egg stains |
US20080090745A1 (en) * | 2006-10-13 | 2008-04-17 | Fox Bryan P | Expression of Streptomyces subtilism inhibitor (SSI) proteins in Bacillus and Streptomyces sp. |
CN103667323B (en) | 2007-03-12 | 2016-02-03 | 丹尼斯科美国公司 | Modified proteolytic enzyme |
MX2009011566A (en) | 2007-04-30 | 2009-11-10 | Danisco Us Inc Genencor Div | Use of protein hydrolysates to stabilize metalloprotease detergent formulations. |
DK2152732T3 (en) | 2007-05-10 | 2012-06-04 | Danisco Us Inc | Modified secretion system to increase expression of polypeptides in bacteria |
JP5629584B2 (en) | 2007-12-21 | 2014-11-19 | ダニスコ・ユーエス・インク | Accelerated protein production in Bacillus |
KR101683302B1 (en) * | 2008-03-28 | 2016-12-06 | 다니스코 유에스 인크. | Method for amplifying locus in bacterial cell |
AR076941A1 (en) | 2009-06-11 | 2011-07-20 | Danisco Us Inc | BACILLUS CEPA FOR A GREATER PROTEIN PRODUCTION |
EP3418382B1 (en) * | 2010-05-06 | 2021-01-20 | Danisco US Inc. | Compositions and methods comprising subtilisin variants |
JP5829844B2 (en) * | 2011-06-24 | 2015-12-09 | 太邦株式会社 | Method for producing water-soluble elastin peptide |
AU2013371614B2 (en) * | 2012-10-01 | 2017-04-13 | Rutgers, The State University Of New Jersey | Precursors and transport methods for hydrothermal liquid phase sintering (HLPS) |
JP2017503061A (en) | 2013-11-11 | 2017-01-26 | エコラボ ユーエスエー インコーポレイティド | Multi-purpose enzyme detergent and method for stabilizing use solution |
JP6585602B2 (en) | 2013-12-31 | 2019-10-02 | ダニスコ・ユーエス・インク | Increased protein expression |
JP7012533B2 (en) | 2014-12-16 | 2022-02-14 | ダニスコ・ユーエス・インク | Enhanced protein expression |
KR20170093247A (en) | 2014-12-19 | 2017-08-14 | 다니스코 유에스 인크. | Enhanced protein expression |
US11021680B2 (en) * | 2016-09-07 | 2021-06-01 | Ecolab Usa Inc. | Detergent compositions containing a stabilized enzyme by phosphonates |
KR102375732B1 (en) | 2017-02-24 | 2022-03-16 | 다니스코 유에스 인크. | Compositions and methods for increasing protein production in Bacillus licheniformis |
EP3655537A1 (en) | 2017-08-23 | 2020-05-27 | Danisco US Inc. | Methods and compositions for efficient genetic modifications of bacillus licheniformis strains |
KR20200047668A (en) | 2017-09-13 | 2020-05-07 | 다니스코 유에스 인크. | Modified 5'-untranslated region (UTR) sequence for increased protein production in Bacillus |
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DK3735478T3 (en) | 2018-01-03 | 2023-10-30 | Danisco Us Inc | MUTANT AND GENETICLY MODIFIED BACILLUS CELLS AND METHODS THEREOF FOR INCREASED PROTEIN PRODUCTION |
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Family Cites Families (25)
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GB1234445A (en) * | 1967-10-03 | 1971-06-03 | ||
US4594362A (en) * | 1983-07-06 | 1986-06-10 | Creative Products Resource Associates, Ltd. | Friable foam textile cleaning stick |
US4980288A (en) * | 1986-02-12 | 1990-12-25 | Genex Corporation | Subtilisin with increased thermal stability |
PT89702B (en) * | 1988-02-11 | 1994-04-29 | Gist Brocades Nv | PROCESS FOR PREPARING NEW PROTEOLITIC ENZYMES AND DETERGENTS THAT CONTAINS THEM |
US5324653A (en) * | 1988-02-11 | 1994-06-28 | Gist-Brocades N.V. | Recombinant genetic means for the production of serine protease muteins |
US5116741A (en) * | 1988-04-12 | 1992-05-26 | Genex Corporation | Biosynthetic uses of thermostable proteases |
AU618675B2 (en) * | 1989-05-17 | 1992-01-02 | Amgen, Inc. | Multiply mutated subtilisins |
US5665587A (en) * | 1989-06-26 | 1997-09-09 | Novo Nordisk A/S | Modified subtilisins and detergent compositions containing same |
DE69034159T2 (en) * | 1989-06-26 | 2005-02-17 | Unilever N.V. | Enzymatic detergent compositions |
JP3220137B2 (en) * | 1989-08-25 | 2001-10-22 | ヘンケル・リサーチ・コーポレイション | Alkaline protease and method for producing the same |
DK164074C (en) * | 1989-08-25 | 1992-09-28 | Poul Ole Fanger | METHOD OF ASSESSING AIR POLLUTION AND APPARATUS FOR EXERCISING THE PROCEDURE |
DE4023458A1 (en) * | 1989-08-31 | 1991-03-07 | Kali Chemie Ag | NEW HIGH ALKALINE PROTEASES |
US5352603A (en) * | 1989-08-31 | 1994-10-04 | Kali-Chemie Ag | Highly alkaline proteases |
DK246290D0 (en) * | 1990-10-12 | 1990-10-12 | Novo Nordisk As | NEW ENZYM |
DE4106525A1 (en) * | 1991-03-01 | 1992-09-10 | Solvay Enzymes Gmbh & Co Kg | METHOD FOR IMPROVING THE STABILITY OF HIGH ALKALINE PROTEASES |
DK58591D0 (en) * | 1991-04-03 | 1991-04-03 | Novo Nordisk As | HIS UNKNOWN PROTEAS |
DE4224125A1 (en) * | 1991-07-27 | 1993-01-28 | Solvay Enzymes Gmbh & Co Kg | METHOD FOR IMPROVING THE STABILITY OF ENZYMS AND STABILIZED ENZYMES |
JPH0763368B2 (en) * | 1991-10-09 | 1995-07-12 | 大阪府 | Heat-resistant alkaline protease and method for producing the same |
DE69333463D1 (en) * | 1992-05-18 | 2004-05-06 | Genencor Int | Bacteria producing alkaline proteases, and process for producing these alkaline proteases |
DE4218448A1 (en) * | 1992-06-04 | 1993-12-09 | Solvay Enzymes Gmbh & Co Kg | Alkaline proteases from Bacillus pumilus |
DE4219104A1 (en) * | 1992-06-11 | 1993-12-16 | Solvay Enzymes Gmbh & Co Kg | Alkaline protease from Bacillus sp. MF12, a process for their preparation and their use |
JP4028592B2 (en) * | 1992-07-17 | 2007-12-26 | ジェネンコー インターナショナル インコーポレイテッド | High alkaline serine protease |
DE4304161A1 (en) * | 1993-02-12 | 1994-08-25 | Solvay Enzymes Gmbh & Co Kg | Improved highly alkaline proteases |
DE4411223A1 (en) * | 1994-03-31 | 1995-10-05 | Solvay Enzymes Gmbh & Co Kg | Use of alkaline proteases in commercial textile washing processes |
US6599730B1 (en) * | 1994-05-02 | 2003-07-29 | Procter & Gamble Company | Subtilisin 309 variants having decreased adsorption and increased hydrolysis |
-
1994
- 1994-03-31 DE DE4411223A patent/DE4411223A1/en not_active Withdrawn
-
1995
- 1995-03-27 DK DK95913164T patent/DK0753058T3/en active
- 1995-03-27 CN CN95193076A patent/CN1148406A/en active Pending
- 1995-03-27 NZ NZ282821A patent/NZ282821A/en unknown
- 1995-03-27 WO PCT/EP1995/001141 patent/WO1995027049A1/en active IP Right Grant
- 1995-03-27 AT AT95913164T patent/ATE269404T1/en not_active IP Right Cessation
- 1995-03-27 EP EP95913164A patent/EP0753058B1/en not_active Expired - Lifetime
- 1995-03-27 EP EP95104454A patent/EP0686692B1/en not_active Expired - Lifetime
- 1995-03-27 DE DE59510341T patent/DE59510341D1/en not_active Expired - Lifetime
- 1995-03-27 BR BR9507237A patent/BR9507237A/en not_active Application Discontinuation
- 1995-03-27 DK DK95104454T patent/DK0686692T3/en active
- 1995-03-27 JP JP7525398A patent/JPH10505741A/en active Pending
- 1995-03-27 CA CA002186764A patent/CA2186764C/en not_active Expired - Lifetime
- 1995-03-27 US US08/716,293 patent/US6190904B1/en not_active Expired - Lifetime
- 1995-03-27 AU AU20731/95A patent/AU710223B2/en not_active Ceased
- 1995-03-27 AT AT95104454T patent/ATE222947T1/en not_active IP Right Cessation
- 1995-03-27 DE DE59510914T patent/DE59510914D1/en not_active Expired - Lifetime
- 1995-03-29 AU AU16175/95A patent/AU705385B2/en not_active Ceased
- 1995-03-30 FI FI951520A patent/FI116681B/en not_active IP Right Cessation
- 1995-03-31 US US08/413,724 patent/US5880080A/en not_active Expired - Lifetime
- 1995-03-31 JP JP7076618A patent/JPH07286194A/en active Pending
- 1995-03-31 BR BR9501401A patent/BR9501401A/en not_active Application Discontinuation
- 1995-03-31 CA CA002146063A patent/CA2146063C/en not_active Expired - Lifetime
-
1996
- 1996-09-25 FI FI963829A patent/FI120739B/en not_active IP Right Cessation
-
1997
- 1997-05-08 US US08/853,494 patent/US6165960A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6187739B1 (en) | 1995-09-21 | 2001-02-13 | Henkel Kommanditgesellschaft Auf Aktien | Paste-form washing and cleaning agents |
US6380140B1 (en) | 1996-04-20 | 2002-04-30 | Henkel Komm.Nditgesellschaft Auf Aktien | Enzyme granules containing phosphated starch |
US6248708B1 (en) | 1996-09-05 | 2001-06-19 | Henkel-Ecolab Gmbh & Co. Ohg | Paste-form detergent containing a mixture of ethoxylated alcohols |
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