CN104653885A - Fireproof pipeline made from new composite material - Google Patents

Fireproof pipeline made from new composite material Download PDF

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Publication number
CN104653885A
CN104653885A CN201510055845.5A CN201510055845A CN104653885A CN 104653885 A CN104653885 A CN 104653885A CN 201510055845 A CN201510055845 A CN 201510055845A CN 104653885 A CN104653885 A CN 104653885A
Authority
CN
China
Prior art keywords
composite material
fireproof
fire
insulating layer
acm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510055845.5A
Other languages
Chinese (zh)
Inventor
陈和龙
孙香头
廖国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIUMEI FIBER GLASS CO Ltd
Original Assignee
JIUMEI FIBER GLASS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIUMEI FIBER GLASS CO Ltd filed Critical JIUMEI FIBER GLASS CO Ltd
Priority to CN201510055845.5A priority Critical patent/CN104653885A/en
Publication of CN104653885A publication Critical patent/CN104653885A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/12Rigid pipes of plastics with or without reinforcement
    • F16L9/133Rigid pipes of plastics with or without reinforcement the walls consisting of two layers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L57/00Protection of pipes or objects of similar shape against external or internal damage or wear
    • F16L57/04Protection of pipes or objects of similar shape against external or internal damage or wear against fire or other external sources of extreme heat

Abstract

The invention discloses a fireproof pipeline made from a new composite material. The fireproof pipeline is characterized by comprising an FRP (Fiber Reinforced Plastic) pipe layer and a fireproof insulating layer arranged at the outer part of the FRP pipe layer, wherein the fireproof insulating layer is made from GP-486G34 phenolic resin as a substrate material, 8-15% of hexamethylenetetramine CGH12N4 is added into the resin matrix material; soaked fibers are twisted on the surface of the a formed FRP pipe to solidify and form after the uniformly mixing. According to the fireproof pipeline provided by the invention, the flame retardant efficiency and the performance parameters of the product can be greatly improved, and the brittleness of the FRP pipe cannot be affected completely when the flame retardant efficiency is improved, therefore the code requirements of the IMO (International Maritime Organization) ISO753. (18) can be completely met, and the excellent fireproof products can be provided to a ship industry.

Description

A kind of advanced composite material (ACM) fire-resisting duct
Technical field
The invention discloses a kind of fire protect duct, be specifically related to a kind of advanced composite material (ACM) fire-resisting duct.
Background technique
At present, the fiber reinforced plastic pipe overwhelming majority on market is non-flame resistant, and some manufacturers add suitable mineral filler as fire retardant in body material, and can play certain fire-retardant, but refractory nature is poor, effect is undesirable.After existing fiber reinforced plastic pipe adds filler in body material, can reach certain fire-retardant, but strengthen due to the own fragility of material after adding filler, refractory nature is poor, and after surperficial calcination, its inner layer glass steel structural layer is damaged, body is of serious failure, more can not meet the requirement of extra large work fire resistant flame retardant.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the invention provides a kind of advanced composite material (ACM) fire-resisting duct.
Technological scheme: for solving the problems of the technologies described above, a kind of advanced composite material (ACM) fire-resisting duct provided by the invention, comprise Glass Steel Tube channel layer and the refractory insulating layer being arranged on Glass Steel Tube channel layer outside, described refractory insulating layer is by GP-486G34 phenolic resin as body material, adds the hexamethylenetetramine C6H12N4 of about 8-15% in reisn base material; After stirring, soak into Filament-wound Machine again in type fiber reinforced plastic pipe surface solidifying, this component is through the optimization of test of many times test gained, and the product after making detects through American Petroleum Institute, and performance meets the requirement of Marine GRP pipeline completely.
Further, the structural formula of described GP-486G34 phenolic resin is:
Further, described n interval [1,10000].
Further, described C 6h 12n 4the mass fraction added in body material is 10-12%.
Beneficial effect: the present invention in terms of existing technologies: the product flame retardant effect provided in the present invention, performance parameter is all greatly improved, and while raising flame retardant effect, the tough of Glass Steel Tube does not reduce, and can not change along with variation of ambient temperature, the complete code requirement that can meet International Maritime Organization ISO753. (18), can provide excellent fire-resistant product for shipbuilding industry.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Embodiment
Below in conjunction with accompanying drawing, the present invention is further described.
As shown in Figure 1, a kind of advanced composite material (ACM) fire-resisting duct, comprise Glass Steel Tube channel layer and the refractory insulating layer being arranged on Glass Steel Tube channel layer outside, described refractory insulating layer is by GP-486G34 phenolic resin as body material, adds the hexamethylenetetramine C6H12N4 of about 8-15% in reisn base material; After stirring, then soak into Filament-wound Machine in type fiber reinforced plastic pipe surface solidifying, the structural formula of described GP-486G34 phenolic resin is:
Embodiment 1:
A kind of advanced composite material (ACM) fire-resisting duct, comprise Glass Steel Tube channel layer and the refractory insulating layer being arranged on Glass Steel Tube channel layer outside, described refractory insulating layer is by GP-486G34 phenolic resin as body material, adds the hexamethylenetetramine C6H12N4 of 8% in reisn base material; After stirring, then soak into Filament-wound Machine in type fiber reinforced plastic pipe surface solidifying.
Embodiment 2:
A kind of advanced composite material (ACM) fire-resisting duct, comprise Glass Steel Tube channel layer and the refractory insulating layer being arranged on Glass Steel Tube channel layer outside, described refractory insulating layer is by GP-486G34 phenolic resin as body material, adds the hexamethylenetetramine C6H12N4 of 15% in reisn base material; After stirring, then soak into Filament-wound Machine in type fiber reinforced plastic pipe surface solidifying.
Embodiment 3:
A kind of advanced composite material (ACM) fire-resisting duct, comprise Glass Steel Tube channel layer and the refractory insulating layer being arranged on Glass Steel Tube channel layer outside, described refractory insulating layer is by GP-486G34 phenolic resin as body material, adds the hexamethylenetetramine C6H12N4 of 10% in reisn base material; After stirring, then soak into Filament-wound Machine in type fiber reinforced plastic pipe surface solidifying.
Embodiment 4:
A kind of advanced composite material (ACM) fire-resisting duct, comprise Glass Steel Tube channel layer and the refractory insulating layer being arranged on Glass Steel Tube channel layer outside, described refractory insulating layer is by GP-486G34 phenolic resin as body material, adds the hexamethylenetetramine C6H12N4 of 12% in reisn base material; After stirring, then soak into Filament-wound Machine in type fiber reinforced plastic pipe surface solidifying.
Embodiment 5:
A kind of advanced composite material (ACM) fire-resisting duct, comprise Glass Steel Tube channel layer and the refractory insulating layer being arranged on Glass Steel Tube channel layer outside, described refractory insulating layer is by GP-486G34 phenolic resin as body material, adds the hexamethylenetetramine C6H12N4 of 11% in reisn base material; After stirring, then soak into Filament-wound Machine in type fiber reinforced plastic pipe surface solidifying.
Drawn in Performance Detection by the finished product prepared embodiment 1 ~ 5,
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (4)

1. an advanced composite material (ACM) fire-resisting duct, it is characterized in that: comprise Glass Steel Tube channel layer and the refractory insulating layer being arranged on Glass Steel Tube channel layer outside, described refractory insulating layer is by GP-486G34 phenolic resin as body material, adds the hexamethylenetetramine C of 8-15% in reisn base material 6h 12n 4; After stirring, then soak into Filament-wound Machine in type fiber reinforced plastic pipe surface solidifying.
2. advanced composite material (ACM) fire-resisting duct according to claim 1, is characterized in that: the structural formula of described GP-486G34 phenolic resin is:
3. advanced composite material (ACM) fire-resisting duct according to claim 2, is characterized in that: described n interval [1,10000].
4. advanced composite material (ACM) fire-resisting duct according to claim 2, is characterized in that: described C 6h 12n 4the mass fraction added in body material is 10-12%.
CN201510055845.5A 2015-02-03 2015-02-03 Fireproof pipeline made from new composite material Pending CN104653885A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510055845.5A CN104653885A (en) 2015-02-03 2015-02-03 Fireproof pipeline made from new composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510055845.5A CN104653885A (en) 2015-02-03 2015-02-03 Fireproof pipeline made from new composite material

Publications (1)

Publication Number Publication Date
CN104653885A true CN104653885A (en) 2015-05-27

Family

ID=53245344

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510055845.5A Pending CN104653885A (en) 2015-02-03 2015-02-03 Fireproof pipeline made from new composite material

Country Status (1)

Country Link
CN (1) CN104653885A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109611644A (en) * 2018-11-28 2019-04-12 苏州久美玻璃钢股份有限公司 A kind of GRP pipe of fire resisting
WO2020107243A1 (en) * 2018-11-28 2020-06-04 苏州久美玻璃钢股份有限公司 Fire-resistant fiberglass reinforced plastic pipe

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2140015Y (en) * 1992-04-03 1993-08-11 陈松 Glass fibre reinforced plastic protecting and insulating shell for pipeline
US5799705A (en) * 1995-10-25 1998-09-01 Ameron International Corporation Fire resistant pipe
CN101532592A (en) * 2009-04-10 2009-09-16 芜湖圣弗兰玻璃钢有限公司 Environmental protection glass-reinforced plastic pipe and production method thereof
CN201513637U (en) * 2009-04-10 2010-06-23 芜湖圣弗兰玻璃钢有限公司 Environmental protection glass-reinforced plastic pipe
CN203770863U (en) * 2014-01-22 2014-08-13 天津盛杰建筑材料有限公司 Portable glass reinforced plastic pipeline

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2140015Y (en) * 1992-04-03 1993-08-11 陈松 Glass fibre reinforced plastic protecting and insulating shell for pipeline
US5799705A (en) * 1995-10-25 1998-09-01 Ameron International Corporation Fire resistant pipe
CN101532592A (en) * 2009-04-10 2009-09-16 芜湖圣弗兰玻璃钢有限公司 Environmental protection glass-reinforced plastic pipe and production method thereof
CN201513637U (en) * 2009-04-10 2010-06-23 芜湖圣弗兰玻璃钢有限公司 Environmental protection glass-reinforced plastic pipe
CN203770863U (en) * 2014-01-22 2014-08-13 天津盛杰建筑材料有限公司 Portable glass reinforced plastic pipeline

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109611644A (en) * 2018-11-28 2019-04-12 苏州久美玻璃钢股份有限公司 A kind of GRP pipe of fire resisting
WO2020107243A1 (en) * 2018-11-28 2020-06-04 苏州久美玻璃钢股份有限公司 Fire-resistant fiberglass reinforced plastic pipe

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Application publication date: 20150527